In this scene from the second episode of Gossip Girl season three, Blair somehow doesn't fit against the dorm backdrop in her Victoria Beckham purple silk minidress. Since her dress is such a bright statement piece, she keeps her accessories simple in a matching Paige Gamble stingray headband and a gold charm bracelet. Leave it to B to dress to the nines, no matter where she's going. Shop now!

Photo courtesy of The CW